Eric Church stopped by the Tonight Show Starring Jimmy Fallon last night (Sept. 12) to perform his new single, “Kill a Word,” with Grammy-winning artist Rhiannon Giddens of the Carolina Chocolate Drops.

After a little playful banter with host Jimmy, Eric got down to business on his new single, the third one from his fifth studio album, Mr. Misunderstood.

Watch the performance below, and if you are unfamiliar with Rhiannon or the Carolina Chocolate Drops, check them out—they are amazing artists and musicians.